超声微波耦合制备P(AM-DMC-BA)及其污泥脱水研究

以丙烯酰胺(AM)为主单体、甲基丙烯酰氧乙基三甲基氯化铵(DMC)为阳离子单体、丙烯酸丁酯(BA)为疏水单体,偶氮二异丁脒盐酸盐(V-50)为引发剂,通过微波和超声耦合技术合成新型高效阳离子共聚物絮凝剂P(AM-DMC-BA)。考察了原料对P(AM-DMC-BA)特性黏度及转化率的影响,P(AM-DMC-BA)对其进行了表征,并用于污泥脱水实验。结果表明,当单体AM、DMC、BA的质量分数分别为22.5%、7.5%、1%,引发剂V-50的质量分数为2%,尿素的质量分数为1.2%,聚合体系pH为3.5,制得的P(AM-DMC-BA)的特性黏度及转化率最高。当共聚物投加量为45 mg/L、污泥溶液pH为7时,其对污泥有较好的脱水性能,且具有良好的pH抗性。     

引入气相对D类颗粒间歇卸料过程特性的影响

通过测量并分析引入气相前后D类颗粒间歇卸料过程中示踪颗粒的流动状态、压力分布和颗粒流率，发现床体内气固两相流动特性不仅随时间变化，还受到气速（正负压差）的影响。据此将卸料过程按时间分为3个阶段：初始蓄压（PS）阶段、稳定卸料（SD）阶段和非满管流（PP）阶段；并给出各卸料阶段不同正、负压差和重力条件下的气固流动特性。在时间较长、流场较为稳定的SD阶段，发现卸料口颗粒阻力是影响颗粒流率的关键参数，通过修正De Jong公式、Beverloo公式，依次建立卸料口颗粒阻力、D类颗粒卸料流率预测模型，与实验值吻合较好，有望为引入气相调控D类颗粒卸料流率的方法提供参考。     

中高温烟气干燥脱硫废水过程研究

脱硫废水零排放(ZLD)已成为现阶段环境治理的趋势,传统的治理方法具有高成本、难维护等缺点,因此提出一种利用中高温烟气干燥电厂脱硫废水的新技术。通过将选择性催化还原(SCR)脱硝后的热烟气引入喷雾干燥器,雾化废水使其与烟气充分接触,经干燥进入空气预热器后的原烟道。结果表明:抽取锅炉烟气量的7%左右可干燥脱硫废水2.5 t,使锅炉热效率降低0.68%左右,影响较小。干燥后烟气酸露点温度从93.20℃提高到96.72℃,不会腐蚀空气预热器等后续工艺设备,同时该技术有利于静电除尘器(ESP)、湿法烟气脱硫(WFGD)系统的运行,利用中高温烟气干燥脱硫废水是可行且有效的技术方法。     

Experimental and optimization of material synthesis process parameters for improving capacity of lithium‐ion battery

New methods for synthesis of active materials have been developed to improve capacity and cycle life performance of lithium‐ion batteries. Past studies have focused on routes of development of materials and new processes, which might not be economical for large‐scale production. In this regard, this study examines a widely employed carbothermal reduction technology for the synthesis of lithium‐iron phosphate (LiFePO₄/C) and investigates effects of process conditions during this synthesis on final battery performance. An experimental combined genetic programming approach is used to model the effects of crucial process conditions (sintering time, the carbon content, and the sintering temperature) on the discharge capacity of the assembled battery. Experiments are conducted to collect the discharge capacity data based on varying LiFePO₄/C synthesis conditions, and genetic programming is employed to develop a suitable functional relationship between them. The results show that the battery discharge capacity is controlled significantly by adjusting sintering temperature and carbon content, while the effect of sintering time is found to be insignificant. Further, the interaction effect of the sintering time and carbon content is much more obvious than that of the sintering time and the sintering temperature. The findings from the study pave the way for the optimum design of the synthesis process of LiFePO₄/C for a higher battery performance.     

Modification of structure and conductivity of nanohorns by toluene addition in carbon arc

Abstract

In the present work, we compare the structure and transport properties of carbon nanohorns (CNHs) synthesized by arc evaporation of graphite alone and with the addition of some portion of toluene. The materials have been investigated using transmission electron microscopy, Raman and infrared spectroscopies, thermogravimetric and BET analyses. The addition of a small amount of toluene during the evaporation of graphitic rod increases the length of CNHs, affects their hierarchical arrangement in aggregates and results in surface functionalization. All these features significantly enhance the conductivity of CNHs obtained with toluene additive in comparison with the pristine CNHs.     

基于水位和水位—流量关系的险情状态分析评估

为了正确分析评估防汛抢险中抢护后的管涌、漏洞等险情状态，根据防汛抢险实践和相关溃口失事案例，分析评估了流量与水位正、负相关时和无法观测流量时水位对险情状态的影响程度。水位的涨落及水位与堤内出险处流量的相关关系，对险情分析与状态评估具有一定的参考价值和提示作用。出险处流量随水位的上涨（下降）而增加（减少）时应注意观测围井内的含沙量和反滤料的变化情况，并排查该处险情附近区域有无新的险情，或已发生的新险情处理后有无异常迹象。     

米象的脉冲微波致死机制研究

为了探讨脉冲微波对米象的致死机制,研究了脉冲微波对米象致死行为、表观形貌及体内碱性磷酸酶和乙酰胆碱酯酶活性的影响。结果表明,脉冲微波处理引起米象死亡、乙酰胆碱酯酶和碱性磷酸酶活性降低、口器和尾部出现异常。米象致死率与米样温度呈显著正相关,当米样温度高于56℃时,米象致死率达100%;米象致死率与乙酰胆碱酯酶活性呈显著负相关,乙酰胆碱酯酶活性低于0.3 U/gpro时,米象的致死率达80%以上。脉冲微波可能通过非热效应与热效应联合作用引起乙酰胆碱酯酶等功能性生物大分子失活及米象口器和尾部等器官异常杀死米象。     

A two-dimensional air streamer discharge model based on the improved Helmholtz equation at low temperature and sub-atmospheric pressure

In this paper, an efficient boundary condition is applied to solve the photoionization rate, and a two-dimensional numerical simulation is carried out for the development and propagation of an air streamer at low temperature and sub-atmospheric pressure. The results show that the new boundary condition improves the calculation accuracy, but the influence of photoionization on the streamer discharge process is not obvious. The discharge current in the development of streamer discharge is defined, and the corresponding expression of the positive and negative streamer discharge current is given. The influence of the electric field exceeding the threshold value on the discharge process is preliminarily introduced. In the process of discharge, only the propagation velocity of the streamer is obviously higher than that of normal temperature and pressure, and the trend of the other parameters is basically the same as that described in the previous paper. The above results give us a deeper understanding of the discharge characteristics under low temperature and sub-atmospheric pressure, which has certain significance for the development of aviation and high voltage engineering.     

Effect of microstructure on discharge performance of Al–0.8Sn–0.05Ga–0.9Mg–1.0Zn (wt%) alloy as anode for seawater-activated battery

The electrochemical performance and discharge behavior of Al–0.8Sn–0.05Ga–0.9Mg–1.0Zn (wt%) alloys in as-cast, homogenized, and annealed states were investigated through electrochemical means, corrosion rate test, and discharge test in a 3.5 wt% NaCl solution. Results suggest that the discharge performance of this alloy is enhanced by rolling and subsequent annealing treatment. This is attributed to the fact that the microstructure of the alloy is greatly improved through rolling and subsequent annealing treatment. The 400°C-annealed alloy exhibits the most excellent discharge activity than alloys in other states, which is due to more regions being activated by a finer and more uniform Sn-rich phase. Furthermore, the anode efficiency of the 400°C-annealed alloy is higher than that of as-cast and homogeneous alloys due to the more uniform distribution of Sn in the aluminum matrix.